| Facility | Type | Phone | Address | |
| Appomattox Primary School | Virginia Preschool Initiative | aemaxwell@acpsweb.com | 434-352-5766 | 185 Learning Ln, Appomattox, VA 24522 |
| Aslan Castle ELC #2 | Licensed Child Day Center | srevis@aslancastleelc.com | 434-424-0704 | 308 Founders Lane, Appomattox, VA 24522 |
| Bible Baptist Church | Religious Exempt | daycare@bbcappomattox.org | 434-841-0922 | 297 Bible Baptist Road, Appomattox, VA 24522 |
| Grace Hills Baptist Church | Religious Exempt | gracehillselc@aol.com | (434) 325-2273 | 4320 Pumping Station Road, Appomattox, VA 24522 |
| Liberty Baptist Church | Religious Exempt | info@libertybconline.org | 434-352-2336 | 1709 Church Street, Appomattox, VA 24522 |
| Memorial United Methodist Church | Religious Exempt | memorialmc5705@gmail.com | 434-352-0108 | 403 Court Street, Appomattox, VA 24522 |
| STEPS, Inc. - Appomattox Head Start | Child Day Center | mlsherry@acpsweb.com | (434) 352-8251 | 176 Kids Pl, Appomattox, VA 24522 |